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研究了在1723K下CO还原CaO-SiO_2-A1_2O_3-Fe_tO渣系。根据CO_2红外分析仪测定的出口气体中CO_2浓度变化,计算了炉渣的表现还原速度常数K_a和还原速度常数K。结果表明,加入Al_2O_3,提高了CaO-SiO_2-Fe_tO的K_a和K值;炉渣碱度不变时,随着Fe_tO含量的增加,K_a呈增加趋势,但K则呈抛物线趋势变化;当FeO的光学碱度∧_FeO为1.0或0.87时,K_a随该四元渣系光学碱度的增加而线性增加,而K则呈递减趋势。用炉渣规则溶液模型计算了CaO-SiO_2-Al_2O_3-Fe_tO四元渣系的Fe_tO活度a_Fe_tO。
The reduction of CaO-SiO_2-Al_2O_3-Fe_tO slag system at 1723 K was studied. According to the change of CO_2 concentration in outlet gas measured by CO_2 infrared analyzer, the reduction rate constant K_a and reduction rate constant K of slag were calculated. The results show that K_a and K of CaO-SiO_2-Fe_tO increase with the addition of Al_2O_3. When the basicity of slag is constant, K_a increases with the increase of Fe_tO content, but K shows a parabolic trend. When basicity ∧_FeO was 1.0 or 0.87, K_a increased linearly with the increase of optical basicity of the quaternary slag, while K showed a decreasing trend. The Fe_tO activity a_Fe_tO of CaO-SiO_2-Al_2O_3-Fe_tO quaternary slag system was calculated by the slag regular solution model.