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共价双金属配合物因其结构的优越性,在分子器件特别是分子导线的研究方面有广阔的应用前景。分子内电子耦合作用的研究是揭示这类配合物构成的分子导线性能的关键之一。本文介绍了共价双金属配合物的分子内电子耦合作用及此类配合物的结构特点,总结了近年来共价双金属配合物在分子导线领域的研究进展,并对共价双金属配合物的发展前景进行了展望。
Covalent bimetallic complexes have broad application prospects in the research of molecular devices, especially molecular conductors due to their structural superiority. The study of intramolecular electronic coupling is one of the keys to reveal the molecular conducting properties of these complexes. In this paper, the intramolecular electronic coupling of covalent bimetallic complexes and the structural features of these complexes are introduced. The progress of covalent bimetallic complexes in the field of molecular conductors has been summarized in recent years. The covalent bimetallic complexes The prospects for the development of the future.