Synthesis and Characterization of Novel Polyarylene Sulfide

• 作 者: CHEN Quanxing YANG Jie LONG Sh
• 机 构: College of Chemistry,Institute of Materials Science & Technology
• 出 处: 武汉理工大学学报（材料科学版）（英文版）
• 发表日期: 2004年期
• 关键词: polyarylene sulfide sulfone imide (PASSI) characterization properties
• 基金项目: 国家高技术研究发展计划(863计划)

A novel polyarylene sulflde, polyarylene sulfide sulfone imide, was polymerized with a new monomer (Dichlorodiimide) and sodium sulflde by taking high temperature (200℃) N-methyl-2-pyrrolidinone (NMP) as solvent. The polymer was characterized by using conventional methods. Physical properties of the polymer, including thermal stability and solubility, were also studied. DSC and TG analyses reveal that the glass transition temperature Tg is equal to 252.4℃ and that the thermal decomposition temperature Td is equal to 484.9℃.