Diffusive gradients in thin films using molecularly imprinted polymer binding gels for in situ measu

来源 :环境科学与工程前沿 | 被引量 : 0次 | 上传用户:yww74
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Urban wastewater is one of main sources for the introduction of antibiotics into the environment.Monitoring the concentrations of antibiotics in wastewater is necessary for estimating the amount of antibiotics discharged into the environment through urban wastewater treatment systems.In this study,we report a novel diffusive gradient in thin films(DGT)method based on molecularly imprinted polymers(MIPs)for in situ measurement of two typical antibiotics,fluoroquinolones(FQs)and sulfonamides(SAs)in urban wastewater.MIPs show specific adsorption toward their templates and their structural analogs,resulting in the selective uptake of the two target antibiotics during MIP-DGT deployment.The uptake performance of the MIP-DGTs was evaluated in the laboratory and was relatively independent of solution pH(4.0-9.0),ionic strength(1-750 mmol/L),and dissolved organic matter(DOM,0-20 mg/L).MIP-DGT samplers were tested in the effluent of an urban wastewater treatment plant for field trials,where three SA(sulfamethoxazole,sulfapyridine,and trimethoprim)and one FQ(ofloxacin)antibiotics were detected,with concentrations ranging from 25.50 to 117.58 ng/L,which are consistent with the results measured by grab sampling.The total removal efficiency of the antibiotics was 80.1%by the treatment plant.This study demonstrates that MIP-DGT is an effective tool for in situ monitoring of trace antibiotics in complex urban wastewaters.
其他文献
会议
会议
母乳喂养可降低新生儿感染性腹泻的发病率陈洪素,陆景云我院1983年7月~1990年10月,共收治新生儿感染性腹泻99例(其中病原为鼠伤寒沙门氏菌49例,致病大肠杆菌50例),均为产科婴儿室发病转住儿科或就地隔
Co-PADAP 石墨炉原子吸收光谱法测定水中微量阴离子表面活性剂张晓光,周维民,张潮用苯萃取阴离子表面活性剂与Co-PADAP形成的络合物,再以石墨炉原子吸收法测定有机相中的Co,间接地测定阴离子表面活
会议
The natural resources consumption has reached unprece-dented levels during the past centuries.Along with the rapid urbanization crossing the world,serious envir
期刊
会议
A high level of ozone(O3)is frequently observed in the suburbs of Shanghai,the reason for this high level remains unclear.To obtain a detailed insight on the hi
会议
A cobalt-based hydrotalcite-like compound was prepared using a constant-pH coprecipitation method.Cobalt-transition metal oxides(Co2XAlO,X = Co,Mg,Ca and Ni)wer