【摘 要】
：
Photocatalytic oxidation of alcohols has received more and more attention in recent years following the numerous studies on the degradation of pollutants,hydrogen evolution,and CO2 reduction by photo-catalysis.Instead of the total oxidation of organics in
【机 构】
：
College of Environmental Science and Engineering,North China Electric Power University,Beijing 10220
论文部分内容阅读
Photocatalytic oxidation of alcohols has received more and more attention in recent years following the numerous studies on the degradation of pollutants,hydrogen evolution,and CO2 reduction by photo-catalysis.Instead of the total oxidation of organics in the degradation process,the photo-oxidation of alcohols aims at the selective conversion of alcohols to produce carbonyl/acid compounds.Promising results have been achieved in designing the catalysts and reaction system,as well as in the mechanistic investigations in the past few years.This review summarizes the state-of-the-art progress in the photo-oxidation of alcohols,including the development of photocatalysts and cocatalysts,reaction conditions including the solvent and the atmosphere,and the exploration of mechanisms with scavengers experi-ment,electron paramagnetic resonance(EPR)and diffuse reflectance infrared Fourier transform(DRIFT)spectroscopy.The challenges and outlook for the further research in this field are also discussed.
其他文献
Lithium-sulfur(Li-S)batteries represent a“beyond Li-ion”technology with low cost and high theoretical energy density and should fulfill the ever-growing requirements of electric vehicles and stationary energy storage systems.However,the sulfur-based conve
ProloguernThe rich scientific heritage of Dangsheng Su contains as sub-stantial fraction his contributions to the field of catalysis with nanostructured carbon materials.Coming from microstructural analysis it became quickly clear that the richness of mor
Lithium(Li)metal attributes to the promising anode but endures the low Columbic efficiency(CE)and safety issues from the inactive Li accumulation.The metallic Li which is isolated from the lithium anode(named dead Li0)consists the major component of the i
Fiber-supercapacitors(FSCs)are promising power sources for miniature portable and wearable electronic devices.However,the development and practical application of these FSCs have been severely hindered by their low volumetric capacitance and narrow operat
Ni-Ga alloy(Ni/Ga atomic ratio of 8),Ni3Ga and Ni5Ga3 intermetallic compounds(IMCs)catalysts were prepared from Ni-Mg-Al-Ga layered double hydroxides(LDHs)for the deoxygenation of methyl esters to hydrocarbons.In the alloy and IMCs,the presence of Ga redu
Lithium-sulfur batteries have been recognised as highly promising next-generation batteries,due to their low cost and high theoretical energy density.Despite numerous advances in this technology over the last decade,its commercialisation is still a challe
The rational modulation of electronic structure is highly desirable to develop an efficient alkaline hydro-gen evolution reaction (HER) catalyst for renewable energy applications.Metal hydroxide such as Ni(OH)2 has been proven useful for promoting alkalin
Demand for efficient and continuous application for high-grid energy storage systems involves the study towards novel battery technologies.Hence,considering the vast naturally available resources of potas-sium all over the world and its encouraging interc
Whoever met Dangsheng Su (D.S.) will remember this encoun-ter with a personality that brought together the unrelated.The Chi-nese Austrian got to know and estimate the fine details of the small German-speaking culture within the Western hemisphere but alw
In this perspective article,the synthesis and thermodynamic properties of aqueous solutions of formate salts(FS,HCO2-)are described in relationship to the concept of H2 carriers.The physiochemical prop-erties of solid FS,aqueous formate solutions,and aque