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本文通过异氰酸酰化反应合成了含有脲基的苯乙炔新型配体及以它作为辅助配体的4′-(对甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物,初步研究了铂(II)络合物的光物理性质,发现由于脲基的存在,当浓度大于3.32×10-5mol/L时铂(II)络合物能够发生分子间簇集.
In this paper, a novel ligand of phenylacetylene containing ureido groups and its 4 ’- (p-methylphenyl) -6-phenyl-2,2’-bi The photophysical properties of the platinum (II) complex were studied preliminarily. It was found that the platinum (II) complex could be obtained at a concentration of more than 3.32 × 10-5mol / L due to the presence of ureido groups Intermolecular clustering occurs.