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环已酮的制备方法,在有机化学实验教科书中,一般都是采用在酸性介质中用重铬酸钾或重铬酸钠氧化环已醇制备。该法缺点较多,除Cr~(6+)污染环境外,尚需乙醚萃取,药品较贵,操作繁琐。在参考国外有关文献资料的启发下,改用漂白粉代替重铬酸盐作氧化剂合成环已酮,并删去乙醚萃取这一步。实验结果表明,效果较好。实验过程中采用四因素三水平的正交试验方法,对乙酸、漂白粉的用量、反应温度,反应时间等因素对合成环已酮的影响进行了探讨,找出了最佳反应条件及影响反应的主要因素。环已酮的得率在65～70％左右,沸程、折光率及红外
Cyclohexanone preparation methods, in organic chemistry textbooks, are generally used in acidic medium with potassium dichromate or sodium dichromate oxidation cyclohexanol preparation. The law has many disadvantages. In addition to Cr ~ (6+) polluting the environment, it still needs ether extraction, the drugs are more expensive and the operation is cumbersome. Inspired by the reference to foreign literature, the use of bleaching powder instead of dichromate as cyclohexanone synthesis cyclohexanone, and delete the ether extraction step. Experimental results show that the effect is better. In the course of the experiment, the factors of the amount of acetic acid and bleaching powder, the reaction temperature and the reaction time were used to investigate the effects of cyclohexanone on the synthesis of cyclohexanone by orthogonal experiment with four factors and three levels. The optimal reaction conditions and the reaction major factor. Cyclohexanone yield of about 65 to 70%, boiling range, refractive index and infrared