论文部分内容阅读
以氯化铜、邻菲罗啉和2-羟基膦酰基乙酸为原料,采用水热法一锅合成了Cu(Ⅰ)和Cu(Ⅱ)两个配合物,即[(CuCl)2(phen)]n(phen,邻菲罗啉)和[Cu(OX)(phen)]n(OX,草酸根),并通过红外光谱、X-射线单晶衍射进行表征。X-射线单晶衍射分析表明[(CuCl)2(phen)]n和[Cu(OX)(phen)]n均为一维链状结构,其中[(CuCl)2(phen)]n中的Cu(Ⅰ)和[Cu(OX)(phen)]n中的配体草酸根通过氧化还原反应“原位”产生。
Cu (Ⅱ) and Cu (Ⅱ) complexes were synthesized by hydrothermal method using cupric chloride, phenanthroline and 2-hydroxyphosphonoacetic acid as raw materials. ] phenanthroline and [Cu (OX) (phen)] n (OX, oxalate) were synthesized and characterized by IR spectroscopy and X-ray single crystal diffraction. X-ray diffraction analysis shows that [(CuCl) 2 (phen)] n and [Cu (OX) (phen)] n are all one- The oxalate ligands in Cu (I) and [Cu (OX) (phen)] n are produced “in situ” through a redox reaction.