论文部分内容阅读
用Mossbauer谱研究了B2结构金属间化合物Fe-40Al及其加Mn或Ti量分别为1,5,10at.-%的合金.在室温下,Fe-40Al及其合金的Mossbauer谱均接近单峰谱线,Fe原子无明显磁矩对加入第三组元的Fe—40Al合金的Mossbauer谱用最小二乘法拟合为两条洛仑兹曲线之和,认为Mn原子既占据Fe原子位置,也占据Al原子位置;而Ti原子优先占据Fe原子位置,超过5at.-%时,才有少量Ti原子占据Al原子位置.
The Mossbauer spectrum was used to study the structure of Fe-40Al intermetallic compound B2 and its addition amount of Mn or Ti were 1,5,10at. -% of the alloy. At room temperature, the Mossbauer spectra of Fe-40Al and its alloys are close to the single peak line, and the Fe atoms have no obvious magnetic moments. The Mossbauer spectra of the Fe-40Al alloy with the third element are fitted by two least squares Lorenz curve that Mn atoms occupy both the position of the Fe atoms, but also occupy the position of Al atoms; and Ti atoms preferentially occupy the position of Fe atoms, more than 5at. -%, only a small amount of Ti atoms occupy Al atoms.