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The bis(nitrito-N) cobalt(III) octaethylporphyrin derivative with the formula [K(18-C-6)(NO2)0.5(H2O)0.5]2 [CoIII(OEP)(NO2)2] (1) (OEP = octaethylporphyrin and 18-C-6 is the crown ether18-crown-6) has been synthesized and characterized by UV-vis, IR and p