【摘 要】
：
The reaction system of diperoxooxalatovanadate {K_3 [VO (O_2)_2-(C_2O_4)]·H_2O, bpV(Oxa)} and imidazole was studied in anaqueous solution by 1D multinuclear (
【机 构】
：
Department of Physics, State Key Laboratory for Physical Chemistry of Solid Surface,Xiamen Universit
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
The reaction system of diperoxooxalatovanadate {K_3 [VO (O_2)_2-(C_2O_4)]·H_2O, bpV(Oxa)} and imidazole was studied in anaqueous solution by 1D multinuclear (~1H, ~(13)C and ~(51)V) NMR,2D NMR diffusion ordered spectroscopy (DOSY), and variabletemperature NMR techniques. It was shown that DOSY was auseful tool for the study of a mixture. All of the ~1H and ~(13)CNMR signals of the peroxovanadate (V) complexes were as-
The reaction system of diperoxooxalatovanadate {K_3 [VO (O_2) _2- (C_2O_4)] · H_2O, bpV (Oxa)} and imidazole was studied in an aqueous solution by 1D multinuclear (~ 1H, V) NMR, 2D NMR diffusion ordered spectroscopy (DOSY), and variabletemperature NMR techniques. It was shown that DOSY was a useful tool for the study of a mixture. All of the ~ 1H and ~ (13) CNMR signals of the peroxovanadate (V ) complexes were as-
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