论文部分内容阅读
以30%H2O2作为氧化剂,(NH4)6Mo7O24·6H2O和CoCl2在水溶液中反应一步合成得到了含三价钴的钼酸盐(NH4)6[CO2Mo10O38H4]·11H2O,并对其进行了单晶结构测定、红外光谱和紫外可见光谱表征。晶体学参数为:单斜晶系,P2(1)空间群,a=10.826(7),b=12.258(9),c=15.548(10),β=95.475(10)°,V=2053.7(2)3,Z=4,D c=3.01 g·cm-3,R1=0.0257,wR2=0.0656(I>2σ),GOF=1.082。
A single crystal structure of molybdate (NH4) 6 [CO2Mo10O38H4] · 11H2O with trivalent cobalt was obtained by one-step reaction of (NH4) 6Mo7O24 6H2O and CoCl2 in aqueous solution using 30% H2O2 as oxidant. , IR and UV-Vis spectra. The crystallographic parameters are: monoclinic, space group P2 (1), a = 10.826 (7) , b = 12.258 (9) , c = 15.548 (10) and β = 95.475 = 2053.7 (2) 3, Z = 4, D c = 3.01 g · cm -3, R1 = 0.0257, wR2 = 0.0656 (I> 2σ), GOF = 1.082.