Hydrothermal Synthesis and Crystal Structure of a Manganese(Ⅱ) Complex:Mn_(1.5)(cbba)_3(phen)

• 作 者: 王志涛 李秀梅 王庆伟
• 机 构: Department of Chemistry,Tonghua Teachers College,Tonghua,Jilin Normal University,Siping,
• 出 处: 结构化学
• 发表日期: 2011年04期
• 关键词: bonding supramolecular triclinic benzoic spectro stacking struc bidentate carbox

A new metal-organic complex Mn1.5(cbba)3(phen)(Hcbba = 2-(4’-chlorine-ben-zoyl)benzoic acid,phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and struc-turally characterized by single-crystal X-ray diffraction,elemental analyses,TG and IR spectro-scopy.The compound crystallizes in triclinic,space group P1 with a = 12.137(2),b = 14.535(3),c = 14.894(3),α = 86.380(3),β = 70.381(3),γ = 72.647(3)°,V = 2360.3(8)3,C107H64Cl6Mn3N4O18,Mr = 2071.14,Dc = 1.457 g/cm3,μ(MoKα) = 0.638 mm-1,F(000) = 1055,Z = 1,the final R = 0.0638 and wR = 0.1905 for 6155 observed reflections(I > 2σ(I)).It exhibits a 3D supramolecular network through hydrogen bonding and π-π stacking interactions.

A new metal-organic complex Mn1.5 (cbba) 3 (phen) (1) has been hydrothermally synthesized and struc- turally characterized by single-crystal X-ray diffraction, elemental analyzes, TG and IR spectro-scopy. The compound crystallizes in triclinic, space group P1 with a = 12.137 (2), b = 14.535 (3), c = 14.894 )  α = 86.380 (3) β = 70.381 (3) γ = 72.647 (3) ° V = 2360.3 (8) 3 C107H64Cl6Mn3N4O18 Mr = 2071.14 Dc = 1.457 g / cm3 MoKα ) = 0.638 mm -1, F (000) = 1055, Z = 1, the final R = 0.0638 and wR = 0.1905 for 6155 reflected reflections (I> 2σ (I)). It exhibits a 3D supramolecular network through hydrogen bonding and π-π stacking interactions.