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  5. Transition metal complexes bearing 2,6-bis(imino)pyridyl:Synthesis, structure, ethylene polymerizati

Transition metal complexes bearing 2,6-bis(imino)pyridyl:Synthesis, structure, ethylene polymerizati

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：lyt0821
【摘 要】
：
A series of new complexes {2,6-bis[1-((2-methyl-4-methoxyphenyl)imino)ethyl]pyridine}MCI2 [M=Fe(Ⅱ) (2), Co(Ⅱ) (3), Ni(Ⅱ) (4), Cu(Ⅱ) (5), Zn(Ⅱ) (6)] have be
【作 者】
：
SU Biyun ZHAO Jianshe SUN Wenh 
【机 构】
：
DepartmentofChemistry
【出 处】
：
中国科学：化学英文版
【发表日期】
：
2005年z1期
【关键词】
：
Bis(imino)pyridine transition metal complex ETHYLENE polymerization/oligomeriza 
【基金项目】
：
This work was supported by the Chinese Acad-emy of Sciences, the National Natural Science Foundation of China (Grant No. 20371039), National Basic Research Program (the 973 Program, No. 2003CB214600),
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A series of new complexes {2,6-bis[1-((2-methyl-4-methoxyphenyl)imino)ethyl]pyridine}MCI2 [M=Fe(Ⅱ) (2), Co(Ⅱ) (3), Ni(Ⅱ) (4), Cu(Ⅱ) (5), Zn(Ⅱ) (6)] have been synthesized. At 25℃, using 500 equiv of methylaluminoxane (MAO), the activities of Fe(Ⅱ), Co(Ⅱ) c
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