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The title complex [CpIr{N(Ph2PS)2}(N3)](N(Ph2PS)2=bis(diphenylthiophosphoryl)amide,Cp=pentamethylcyclopentadienyl) has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P21/n with a=11.6946(1),b=18.9273(2),c=15.7859(1),β=105.731(1)°,V=3363.29(5)3,Z=4,Mr=817.92,Dc=1.615g/cm3,μ(MoKα)=4.219 mm-1,F(000)=1624,S=1.028,the final R=0.0355 and wR=0.0848 for 5987 observed reflections with Ⅰ > 2σ(Ⅰ) and 363 variables.The molecular structure of 1 consists of discrete monomeric molecule with a distorted octahedral configuration around the iridium atom,having a Cp ring at one face and bonded with a chelating bis(diphenylthiophosphoryl)amide group as well as a terminal azido ligand.The average Ir-S and Ir-N bond lengths are 2.416(1) and 2.121(5),respectively.
The title complex [CpIr {N (Ph2PS) 2} (N (Ph2PS) 2 = bis (diphenylthiophosphoryl) amide, Cp = pentamethylcyclopentadienyl has been prepared and characterized by X-ray diffraction analysis. It crystallizes in monoclinic, Space group P21 / n with a = 11.6946 (1), b = 18.9273 (2), c = 15.7859 (1) β, β = 105.731 (1) °, V = 3363.29 = 817.92, Dc = 1.615g / cm3, μ (MoKα) = 4.219 mm-1, F (000) = 1624, S = 1.028, the final R = 0.0355 and wR = 0.0848 for 5987 observed reflections with I> ) and 363 variables. The molecular structure of 1 consists of discrete monomeric molecule with a distorted octahedral configuration around the iridium atom, having a Cp ring at one face and bonded with a chelating bis (diphenylthiophosphoryl) amide group as well as a terminal azido ligand The average Ir-S and Ir-N bond lengths are 2.416 (1) and 2.121 (5) , respectively.