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本文采用Saveant-Andrieux电催化反应动力学理论,表征了SO_3~(2-)在经Nation-Os(bpy)_3~(2+/3+)修饰后的玻碳电极上的电催化体系的动力学行为,用动力学区域图确定体系的动力学类型.当反应物浓度从8×10~(-5)变至1.28×10~(-3)(mol/L)时,体系始终遵循“SR”的动力学行为。
In this paper, Saveant-Andrieux electrocatalytic kinetic theory is used to characterize the kinetics of SO_3 ~ (2-) electrocatalysis on a glassy carbon electrode modified by Nation-Os (bpy) _3 ~ (2 + / 3 + The kinetic type of the system was determined by kinetic map, and the system always followed the “SR” curve when the reactant concentration was changed from 8 × 10 -5 to 1.28 × 10 -3 mol / L, "Of the dynamic behavior.