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39种仲醇类化合物衍生物在全甲基β-环糊精上得到拆分,并进一步讨论了衍生基团,手性碳在碳链上的位置,碳链的长度等因素对对映体选择性的影响规律.发现在所拆分的仲醇类对映体中,异丁酰化衍生物的对映体选择性明显变差.
39 kinds of secondary alcohol derivatives were resolved on the whole methyl β-cyclodextrin, and the derivatives, the position of the chiral carbon in the carbon chain, the length of the carbon chain and other factors on enantiomer Selectivity of the law of influence was found in the separation of the secondary alcohol enantiomers, isobutyrylated derivatives significantly decreased the enantioselectivity.