Synthesis and Crystal Structure of a Zeolite-like Metal-organic Framework Based on the Triazole Liga

• 作 者: LI Dong-Ping LIANG Xiao-Qiang
• 机 构: DepartmentofChemistry,StateKeyLaboratoryofCoordinationChemistry,CollegeofChemistryandChemicalEnginee
• 出 处: 结构化学
• 发表日期: 2013年11期
• 关键词: 连三唑 类金属 合成基 晶体结构 骨架 沸石 配体 X-射线衍射分析 triazole crystal structure zeolite-like fra
• 基金项目: This work was supported by the National Natural Science Foundation of China （21101090）, the Natural ScienceFoundation of Jiangxi Province （20114BAB213001 ） and the Education Department of Jiangxi Prov

A novel zeolite-like metal-organic framework,[Cd12(trz)12·F10·(SiF6)3]·(H3O)4(Htrz=1,2,4-triazole),has been synthesized under solvothermal conditions using 1H-1,2,4-triazole-3-carboxylic acid and CdF2as the starting materials.The complex ha