Synthesis, Structure and Photoluminescence of a New Cadmium（Ⅱ） Complex Involving in situ Decarboxy

• 作 者: CHEN Lan-Fen QIN Ye-Yan LI Zha
• 机 构: StateKeyLaboratoryofStructuralChemistry
• 出 处: 结构化学
• 发表日期: 2009年2期
• 关键词: 镉配位化合物 吡嗪-2 3-二羧酸酯 去碳酸基 光致发光 结构分析 cadmium pyrazine-2 3-dicarboxylate decarboxy
• 基金项目: This work was supported by the State Key Basic Research and Development Plan of China （2007CB815302）, the Chinese Academy of sciences（KICX2-YW-M05）, the Knowledge Innovation Program of the Chinese Aca

A new luminescent dinuclear cluster complex [Cd2(pzc)2(AmTAZ)(H2O)4(NO3)]·NO3 (Hpzc = pyrazine-2-carboxylic acid, AmTAZ = 3-amino-4H-1,2,4-triazole) has been prepared by the assembly of CdII with pyrazine-2,3-dicarboxylic acid and 3-amino-1H-1,2,4-tr