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A two-dimensional coordination polymer, [Cd(AIP)(Bpy)]n·nBpy, was hydrother- mally synthesized by the reaction of hydrate cadmium acetate with 5-aminoisophthalic acid, lithium hydroxide, vanadiumpentoxide, sodium chloride and 2,2′-bipyridyl in water solution. It crystallizes in orthorhombic, space group C2221, absolute structure parameter 0.00(7), with a = 15.336(4), b = 22.390(6), c = 14.257(3) , V = 4896(2)3, C28H21CdN5O4, Mr = 603.90, Z = 8, F(000) = 2432, Dc = 1.639 g/cm3, μ = 0.939 mm–1, T = 298(2) K, S = 1.001, R = 0.0296 and wR = 0.0813 for 5522 observed reflections (I > 2σ(I)). In the title complex, each 5-aminoisophthalate ligand bridges three cadmium(II) ions to form a two-dimensional layer structure.
A two-dimensional coordination polymer, [Cd (AIP) (Bpy)] n · nBpy, was hydrother- mally synthesized by the reaction of hydrate cadmium acetate with 5-aminoisophthalic acid, lithium hydroxide, vanadium pentoxide, sodium chloride and 2,2 ’ Bipyridyl in water solution. It crystallizes in orthorhombic space group C2221 with an absolute structure parameter of 0.00 (7) with a = 15.336 (4), b = 22.390 (6), c = 14.257 2 = ,3, C28H21CdN5O4, Mr = 603.90, Z = 8, F (000) = 2432, Dc = 1.639 g / cm3, μ = 0.939 mm-1, T = 298 (2) 0.0296 and wR = 0.0813 for 5522 observed reflections (I> 2σ (I)). In the title complex, each 5-aminoisophthalate ligand bridges three cadmium (II) ions to form a two-dimensional layer structure.