PREPARATION OF POLYMER—SUPPORTED RCpCpTiCl2 AND APPLICATION IN CATALYTIC ISOMERIZATION OF 1,5—HEX

• 作 者: QIANYanlong HONGKunlun 等
• 机 构: LaboratoryofOrganometallicChemistry,LaboratoryofOrganometallicChemistry
• 出 处: 中国反应性高分子：英文版
• 发表日期: 1993年2期
• 关键词: 制备 异构化作用 聚合物-支撑烷基环戊二烯基环戊二烯基二氯化钛 1 5-己二烯

Polymer-supported RCpCpTiCl2(Cp=η^5-C5H4;RCp=η^5-RC5H4)have been prepared and reduced by i-C3H7MgBr in situ，then used in catalytic isomerization of 1,5-hexadiene.The isomerization of 1,5-hexadiene leads to a mixture of cyclic and linear products.The ratio