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The natural gas from the Triassic Feixianguan Formation of Northeast Sichuan Basin contains high H2S whereas relatively low CO2 concentrations and the CO2 display high δ13C values (ranging from -5.81‰ to 3.3‰ (PDB)). This seems to contradict the conventional wisdom that TSR should be a primary source of CO2 in natural gas from the Feixianguan Formation. In contrast, many authigenic calcite samples from these sites display very low δ13C values (ranging from -18.4‰ to -10.3‰ (PDB)). This suggests that the carbon from TSR source dominated the formation of calcite whereas the carbon from inorganic source came into CO2 in natural gas. In order to assess the origin of CO2 from these H2S-rich sites, we have calculated the relative contributions of organic and inorganic carbon sources to the CO2 and authigenic calcite. The organic carbon source possibly originated from TSR, whereas the inorganic one might be generated from marine carbonates dissolution. This calculation is based on the carbon isotopic compositions of CO2 and authigenic calcite as well as an isotopic mass balance. The results show that the contribution of organic carbon source to the CO2 is only 2%, whereas that to authigenic calcite is as high as 43% on average. Such results combined with thermodynamic evidence indicate that the isotopically light CO2 produced by TSR process may contribute to authigenic calcite precipitation during burial diagenesis. Distinguishable from Ordovician reservoir of Tarim Basin, Feixianguan reservoir of Northeast Sichuan Basin experienced rapid tectonic uplift due to Yanshanian movement after TSR occurred. Such tectonic event could induce temperature decrease and further promote carbonates dissolution. During these processes, secondary porosity has developed in Feixianguan carbonate reservoirs. Therefore, much attention should be paid to the structural highs in search of high quality carbonate reservoirs.
The natural gas from the Triassic Feixianguan Formation of Northeast Sichuan Basin contains high H2S-prone carbon dioxide concentrations and the CO2 display high δ13C values ranging from -5.81 ‰ to 3.3 ‰ (PDB). This seems to contradict the conventional wisdom that TSR In contrast, many authigenic calcite samples from these sites display very low δ13C values ranging from -18.4 ‰ to -10.3 ‰ (PDB). This suggests that the carbon from TSR source dominated the formation of calcite versus the carbon from inorganic source came into CO2 in natural gas. In order to assess the origin of CO2 from these H2S-rich sites, we have calculated the relative contributions of organic and inorganic carbon sources to the CO2 and authigenic calcite. The organic carbon source originated from TSR, and the the one of the inorganic one might be generated from marine carbonates dissolution. This calculation is based on t he results isotope compositions of CO2 and authigenic calcite as well as an isotopic mass balance. The results show that the contribution of organic carbon source to the CO2 is only 2%, that that that authigenic calcite is as high as 43% on average. results combined with thermodynamic evidence indicate that the isotopically light CO2 produced by TSR process may contribute to authigenic calcite precipitation during burial diagenesis. Distinguishable from Ordovician reservoir of Tarim Basin, Feixianguan reservoir of Northeast Sichuan Basin experienced rapid tectonic uplift due to Yanshanian movement after TSR Such tectonic event could induce temperature decrease and further promote carbonates dissolution. During these processes, secondary porosity has developed in Feixianguan carbonate reservoirs. Thus, much attention should be paid to the structural highs in search of high quality carbonate reservoirs.