Syntheses, Crystal Structures and Properties of Two New W-Ag 1D Chain Complexes：[W2Ag2S8·Ca（DMF

• 作 者: LIYa-Min XIASheng-Qing ZHANGJi
• 机 构: StateKeyLaboratory.ofStructuralChemistry
• 出 处: 结构化学
• 发表日期: 2005年6期
• 关键词: and Crystal Chain NEW linear show the data are NEW may W/Ag/S complexes linear
• 基金项目: 国家重点实验室基金，中国科学院资助项目，中国科学院自然科学基金

Two new complexes, [W2Ag2S8(Ca(DMF)6]n 1 and [WAgS4(Na(DMF)3]n 2, have been synthesized and characterized. Single-crystal X-ray analyses show both 1 and 2 have {WAgS4}n anion linear chains, but 1 has a discrete [Ca(DMF)6]2+ cation while 2 is a linear chai