【摘 要】
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In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide(DPMAA) were studied with living helix
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
In this paper, the helix-sense-selective polymerization of N,N-diphenyl acrylamide (DPAA) and N,N-diphenyl methacrylamide(DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical properties of the obtained polymers were investigated too. It was shown that optically active polymers of DPAA and DPMAA could be obtained under the experimental condition, and exhibited the same screw sense as that of the prepolymer.
In this paper, the helix-sense-selective polymerization of N, N-diphenyl acrylamide (DPAA) and N, N-diphenyl methacrylamide (DPMAA) were studied with living helix prepolymer as anionic initiator, and the chiral optical properties of the obtained polymers were investigated too. It was shown that the optically active polymers of DPAA and DPMAA could be obtained under the experimental condition, and drawings the same screw sense as that of the prepolymer.
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