Gas sensitivity of polyaniline/SnO_2 hybrids to volatile organic compounds

来源 :Transactions of Nonferrous Metals Society of China | 被引量 : 0次 | 上传用户:gxx756_3476
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Polyaniline (PAn) was prepared by chemical oxidation polymerization and characterized by FT-IR. PAn/SnO2 materials with different mass fractions of PAn were prepared by mechanical mixing. Compared with single PAn and SnO2, the gas sensitivity of PAn/SnO2 materials to volatile organic compounds (VOCs, methanol, ethanol and acetone) was studied. The possible response mechanism of PAn/SnO2 materials to VOCs was also discussed. It is found that PAn/SnO2 materials have gas sensitivity to VOCs at 90 ℃ among the four operating temperatures (room temperature, 30, 60 and 90 ℃), but PAn and SnO2 have no gas sensitivity at the above temperatures. The sensitivity of PAn/SnO2 materials shows linear increase with the increase of methanol concentration, but saturation with the increase of ethanol and acetone concentrations. PAn/SnO2 materials have high selectivity, fast response-recovery time and low operation temperature to VOCs, but pure PAn and SnO2 do not have. Compared with single PAn and SnO2, the gas sensitivity of PAn / SnO2 materials to volatile (PAn) / SnO2 materials with PAn / SnO2 materials with different mass fractions of PAn were prepared by mechanical mixing The possible response mechanism of PAn / SnO2 materials to VOCs was also discussed. It is found that PAn / SnO2 materials have gas sensitivity to VOCs at 90 ℃ among the four operating temperatures (room temperature, 30, 60 and 90 ° C), but PAn and SnO2 no no gas sensitivity at the above temperatures. The sensitivity of PAn / SnO2 materials shows linear increase with the increase of methanol concentration, but saturation with the increase of ethanol and PAn / SnO2 materials have high selectivity, fast response-recovery time and low operation temperature to VOCs, but pure PAn and SnO2 do not have.
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