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报道了配合物[Cu(Pic)2].2H2O的制备过程,并详细研究了配合物的磁性和热分解动力学行为.磁性研究表明,化合物具有良好的铁磁性,化合物的热分解过程显示主反应是一级反应,分解动力学可表示为:dα/dt=A(1-α)n.αa.exp(-E/RT).
The preparation process of [Cu (Pic) 2] 2H2O has been reported and the magnetic and thermal decomposition kinetics of the complex has been studied in detail. Magnetic studies show that the compound has good ferromagnetism and the thermal decomposition of the compound shows that The reaction is a first-order reaction, decomposition kinetics can be expressed as: dα / dt = A (1-α) n.αa.exp (-E / RT).