【摘 要】
：
The title complex [Zn(L)(phen)(CH3OH)] (L= C8H6BrO4NS, aminomethanesulfonic acid 5-bromo-salicylaldelyde schiff base; phen = 1,10-phenanthroline) has been synth
【机 构】
：
Department of Chemistry and Material Science
论文部分内容阅读
The title complex [Zn(L)(phen)(CH3OH)] (L= C8H6BrO4NS, aminomethanesulfonic acid 5-bromo-salicylaldelyde schiff base; phen = 1,10-phenanthroline) has been synthesized and characterized by X-ray diffraction method. The crystal belongs to monoclinic, space group P21/c with a = 1.8712(3), b = 1.38008(19), c = 0.83685(12) nm, β = 97.791 (2)°, Mr = 569.72, V = 2.1411(5)nm3,Z= 4, Dc = 1.767 g/cm3, μ = 3.151 mm-1, F(000) = 1144, the final R = 0.0402 and wR = 0.0885. The central Zn(Ⅱ) is six-coordinated by one nitrogen and two oxygen atoms from the Schiff base, two nitrogen atoms from 1,10-phenanthroline and one oxygen from methanol to form a distorted octahedral coordination geometry.
其他文献
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
The title adduct (C9H11N3O6, Mr = 257.21) was synthesized and it crystallizes in orthorhombic, space group P212121 with a = 5.8835(19), b = 9.517(3), c = 20.399
A series of acyls (Ac, Bz and Ts) were introduced regioselectively to the 2-hydroxyl in methyl and ally 3-O-benzyl-α-L-rhamnopyranosides mediated by silver(Ⅰ)
We propose a simple scheme for implementing Deutsch-Jozsa algorithm in cavity QED. Our scheme is insensitive to both the cavity decay and thermal field because
Teleportation schemes with a tripartite entangled state in cavity QED are investigated. The schemes do not need Bell state measurements and the successful proba
The title compound 1,5-diphenyl-3-phenacylthio-1 H-1,2,4-triazole 2 (C22H17N3OS, Mr = 371.45) was prepared by the reaction of l-benzoyl-3-phenyl-aminothiourea 1
Considering the viscoelastic memory effect, we study the correlated motion of two hydrodynamically coupled colloidal particles, each of which confined in a harm
Quasi-interpenetrating network formed by polyacrylamide and poly (N-hydroxymethylacrylamide) was designed, synthesized, and tested for DNA sequencing by capilla
A new hapten, aldicarb oxime succinic ester (AOSE), was synthesized for immunoassay of aldicarb. It was conjugated to proteins by active ester method. Polyclona
An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for rapid simultaneous determination of Be, Mg, Al, Ti, V, C