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报导了四种新的双核钴(Ⅱ)配合物,即[Co2(4I-TPHA)(L)4](COl4)(4I-TPHA=四碘代对苯二甲酸根阴离子,L=1,10菲咯啉(phen)(1),5-硝基-,10菲咯啉(NO2-phen)(2),2,2′-联吡啶(bpy)(3)和4,4′-二甲基-2,2′-联吡啶(Me2bpy)(4)的合成和表征,配合物的磁性研究表明双核钴(Ⅱ)离子间有弱的反铁磁性自旋交换相互作用。
Four new binuclear cobalt (II) complexes have been reported as [Co2 (4I-TPHA) (L) 4] (COI4) (4I-TPHA = tetraiodo-terephthalate anion, L = (Phen) (1), 5-nitro-, 10 phenanthroline (NO2-phen) (2), 2,2’- bipyridine (3) and 4,4’- The synthesis and characterization of 2,2’-bipyridyl (Me2bpy) (4) showed that the magnetic study of the complex showed a weak antiferromagnetic spin exchange interaction between the binuclear cobalt (Ⅱ) ions.