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硫酸氢钠能代替硫酸作为酯化作用催化剂.探讨了一水硫酸氢钠为催化剂,由1-萘乙酸和甲醇酯化合成1-萘乙酸甲酯的优化条件.当1-萘乙酸、甲醇和硫酸氢钠的质量比为1:32:0.8,回流反应7小时,酯收率可达96%.
Sodium bisulfate can replace sulfuric acid as esterification catalyst. The optimal conditions for the synthesis of methyl 1-naphthylacetate from 1-naphthaleneacetic acid and methanol by sodium bisulfate monohydrate as catalyst were discussed. When the mass ratio of 1-naphthalene acetic acid, methanol and sodium bisulfate was 1: 32: 0.8, the reaction was refluxed for 7 hours, the yield of ester reached 96%.