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A new organic-inorganic hybrid material [Na6(H2O)16(dod)2V10O28] (dod = 1,4- diazoniabicyclo[2,2,2]octane-1,4-diacetate) has been synthesized and X-ray single-crystal structural analysis reveals it crystallizes in triclinic, space group P with a = 11.533(7), b = 12.031(7), c = 12.187(4) ? a = 72.47(1), b = 73.16(1), g = 68.21(1)o, C20H64N4Na6O52V10, V = 1467(1) ?, Z = 1, Mr = 1840.1, Dc = 2.083 g/cm3, MoKa, l = 0.71073 ? m = 1.686, F(000) = 924, S = 1.027, the final R = 0.0538 and wR = 0.1272 for 4398 observed reflections. The compound has a three-dimensional frame- work constructed from decavanadate clusters, NaO chains and dod ligands. A variety of OH…O and CH…O hydrogen bonds play an important role in stabilizing the framework.
A new organic-inorganic hybrid material [Na6 (H2O) 16 (dod) 2V10O28] (dod = 1,4- diazoniabicyclo [2,2,2] octane-1,4- diacetate) has been synthesized and X- ray single- The crystal structure analysis reveals it crystallizes in triclinic, space group P with a = 11.533 (7), b = 12.031 (7), c = 12.187 (4)? a = 72.47 (1), b = 73.16 68.21 (1) o, C20H64N4Na6O52V10, V = 1467 (1)? Z = 1 Mr = 1840.1 Dc = 2.083 g / cm3 MoKa = 0.71073? M = 1.686 F000 = 924 S = 1.027, the final R = 0.0538 and wR = 0.1272 for 4398 observed reflections. The compound has a three-dimensional frame-work constructed from decavanadate clusters, NaO chains and dod ligands. A variety of OH ... O and CH ... O hydrogen bonds play an important role in stabilizing the framework.