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在分析各种物质时,非水介质中有机化合物的滴定法得到了广泛的应用。許多物质在非水溶液中的性质,跟在水溶液中不同。有时完全是另一种性质。视溶剂的不同,同一种物质既可以是酸,也可以是碱,还可以是盐。很多有机溶剂能对酸和碱产生分异作用,因此不单能研究单独的酸和碱,而且可以研究酸或碱的多元混合物。例如克列什考夫等人在研究用氢氧化四乙銨在有机溶剂介质中滴定醋酸和苯甲酸的酚衍生物以及它們与其它有机酸和无机酸混合物时确定:在丁酮的介质中可
In the analysis of various substances, non-aqueous media titration of organic compounds has been widely used. The nature of many substances in non-aqueous solutions is different from that in aqueous solutions. Sometimes it is entirely another property. Depending on the solvent, the same substance can be either acid or base, but can also be a salt. Many organic solvents can have a disproportionate effect on acids and bases, and therefore not only individual acids and bases, but also multiple mixtures of acids or bases can be studied. For example, Krieshkov et al., When investigating the titration of phenol derivatives of acetic acid and benzoic acid with tetraethylammonium hydroxide in an organic solvent medium and their mixtures with other organic and inorganic acids, confirm that in a medium of butanone