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A new Ag(I) coordination polymer,{[Ag(l,3-BIP)(H_2O)][Ag(l,3- BIP)(PMA)_(0.5)·-4H_2O}_n(PMA = 1,2,4,5-benzenetricarboxylic acid,1,3-BIP = l,3-bis(imidazole)propane),have been synthesized and characterized by single-crystal X-ray diffraction,powder XRD,FTIR,TGA and elemental analysis techniques.The single-crystal X-ray diffraction reveals that the title complex is formed by 1D polymeric cationic chains of[Ag(l,3-BIP)(H_2O)]_n~(n+) and 2D polymetric anionic layer of[Ag(l,3-BIP)(PMA)_(0.5]_n~(n-),which are further linked by intermolecular H-bonding to form a3 D supramolecular framework.In addition,the photoluminescence property of the title complex in the solid state at room temperature was also investigated.
A new Ag (I) coordination polymer, {[Ag (l, 3-BIP) (H 2 O)] [Ag (l, 3- BIP) (PMA) _ (0.5) · -4H_2O} _n (PMA = 1,2 , 4,5-benzenetricarboxylic acid, 1,3-BIP = l, 3-bis (imidazole) propane, have been synthesized and characterized by single-crystal X-ray diffraction, powder XRD, FTIR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that the title complex is formed by 1D polymeric cationic chains of [Ag (l, 3-BIP) (H 2 O)] n + (n + 3-BIP) (PMA) _ (0.5] _n ~ (n -), which are further linked by intermolecular H-bonding to form a3D supramolecular framework.In addition, the photoluminescence property of the title complex in the solid state at room temperature was also investigated.