Synthesis,characterization and catalytic properties of Y-β zeolite composites

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Y-β zeolite composites were hydrothermally synthesized by using high silica Y zeolite as the precursor and characterized by XRD,N2 adsorption,SEM and IR spectra of pyridine.The result showed that the N2 adsorption-desorption isotherm of the zeolite composites had a distinct hysteresis loop,and the SEM result showed that the zeolite composites had a different morphology from Y,β and the corresponding physical zeolite mixture.The acid catalytic performance of the zeolite composite catalysts was investigated in the hydrocracking and hydroisomerization of n-octane,and the results showed that the composite materials exhibited an excellent hydrocracking activity and good hydroisomerization performance.The yield of i-C4 over the zeolite composite catalyst was 4.45% higher than that on the corresponding zeolite mixture in the n-octane hydrocracking process at 553 K.The isomerization ability of n-octane over the composite catalyst was 3.6 fold that of the corresponding mixture at 503 K. Y-β zeolite composites were hydrothermally synthesized by using high silica Y zeolite as the precursor and characterized by XRD, N2 adsorption, SEM and IR spectra of pyridine. Result showed that the N2 adsorption-desorption isotherm of the zeolite composites had a distinct hysteresis loop, and the SEM result showed that the zeolite composites had a different morphology from Y, β and the corresponding physical zeolite mixture. The acid catalytic performance of the zeolite composite catalysts was investigated in the hydrocracking and hydroisomerization of n-octane, and the results showed that the composite materials exhibited an excellent hydrocracking activity and good hydroisomerization performance. The yield of i-C4 over the zeolite composite catalyst was 4.45% higher than that on the corresponding zeolite mixture at the n-octane hydrocracking process at 553 K. The isomerization ability of n-octane over the composite catalyst was 3.6 fold that of the corresponding mixture at 503 K.
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