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A novel compound, (HGly)4[HPMo12O40]2*22H2O, was synthesized and characterized by means of elemental analysis, IR and X-ray diffraction. The compound crystallized in a monoclinic space group Cc with a=4.0060(0.8) nm, b=1.2527(0.3) nm, c=1.9930(0.4) nm, β=