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The reaction of Ni(CH3COO)2(4H2O, Na2MoO4(H2O, MoO3, 1,10-phenanthroline and 1,4-butylenediphosphonic acid in distilled water at 180 ℃ for 72 h produced two new com- pounds: {[Ni(1,10-phen)3][Ni(1,10-phen)2(Mo6O18)(O3P(CH2)4PO3)](6H2O}n 1 in 15% yield and {[Ni(1,10-phen)2(H2O)2][Ni(1,10-phen)2 (H2O)(Mo5O15)(O3P(CH2)4 PO3)](6H2O}n 2 in 47% yield. 1 and 2 both feature {MonO3nO3P(CH2)4PO3}4- (n = 5, 6) 1-D anionic chain, which is further decorated and charge compensated by [Ni(1,10-phen)2]2+. 1 contains {Mo6O24P2} cluster constructed of three pairs of face-sharing {MoO6} octahedra linked through corner-sharing interaction. 2 exhibits the characteristic structure based on pentanuclear ring of corner- and edge-sharing {MoO6} octahedra capped by three oxygen atoms of {PO3} on each side. The thermogravimetric analyses and magnetic property of 2 were also studied.
The reaction of Ni (CH3COO) 2 (4H2O, Na2MoO4 (H2O, MoO3, 1,10-phenanthroline and 1,4-butylenediphosphonic acid in distilled water at 180 ℃ for 72 h produced two new com pounds: {[Ni , 10-phen) 3] [Ni (1,10-phen) 2 (Mo6O18) (O3P (CH2) 4PO3]] H 2 O 2] 2] [Ni (1,10-phen) 2 (H 2 O) (Mo 5 O 15) (O 3 P (CH 2) 4 PO 3]] (6 H 2 O} n 2 in 47% yield 1 and 2 both feature {MonO3nO3P (CH2) 4PO3 } 4- (n = 5, 6) 1-D anionic chain, which is further decorated and charge compensated by [Ni (1,10-phen) 2] 2+. 1 contains {Mo6O24P2} cluster constructed of three pairs of face -sharing {MoO6} octahedra linked through corner-sharing interaction. 2 exhibits the characteristic structure based on pentanuclear ring of corner- and edge-sharing {MoO6} octahedra capped by three oxygen atoms of {PO3} on each side. The thermogravimetric analyzes and magnetic property of 2 were also studied.