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In this article we report the synthesis of (R,S)-4,4′-biquinoline-6,6′-dimethyl-3,3′-dicarboxylate (DBBD) (1) and the formation of copper(Ⅰ) coordination polymer [CuI(DBBD)_2]_n (2) by inducing a bidentate organic ligand (DBBD). The crystal 1 belongs to m