【摘 要】
：
研究了标题配合物的红外光谱和热稳定性。红外光谱分析结果表明,配位的2,2′-二氨基-4,4′-联噻唑的噻唑环和氨基上的两个氮的异构化交换引起的骨架振动由1342cm-1红移至1298
【机 构】
：
盘锦职业技术学院教务处 辽宁省盘锦市兴隆台区惠宾大街119号124010
论文部分内容阅读
研究了标题配合物的红外光谱和热稳定性。红外光谱分析结果表明,配位的2,2′-二氨基-4,4′-联噻唑的噻唑环和氨基上的两个氮的异构化交换引起的骨架振动由1342cm-1红移至1298cm-1。热分析结果表明,配合物在135℃附近先失去两个结晶水,在314℃附近甘氨酸羧基中C—O(配位)键断裂,配合物失去两个甘氨酸阴离子部分,配合物的剩余部分则在320℃以后继续以缓慢的速率进行放热分解。
The infrared spectra and thermal stability of the title complex were studied. The results of FTIR showed that the vibration of the framework caused by the isomerization exchange between the thiazole ring of the coordinating 2,2’-diamino-4,4’-bithiazole and the two nitrogens on the amino group was red-shifted from 1342cm-1 to 1298cm-1. The results of thermal analysis showed that the complex lost two crystal water near 135 ℃ and the C-O (coordination) bond was broken at the carboxyl group of glycine near 314 ℃. The remaining part of the complex lost two glycine anion After 320 ℃ continue to carry out exothermic decomposition at a slow rate.
其他文献
复方替米沙坦胶囊为中国人民解放军第454医院研制的、由非肽类血管紧张素Ⅱ受体拮抗剂替米沙坦和利尿剂吲达帕胺组成的复方制剂,适用于轻、中度高血压。临床试验表明,两药合
三唑类化合物具有广泛的生物活性.以2-羟基-5,7-二甲基-l,2,4-三唑并[1,5-a]嘧啶为原料,在缚酸剂存在下,于室温分别和苯磺酰氯、对甲苯磺酰氯进行酯化反应,合成了两个新型的5
在水热法制备TiO2胶体的基础上,加入松油醇、聚丙烯酸酯、Tx-100、乙基纤维素组成浆液,利用丝网印刷技术制备了染料敏化纳晶多孔TiO2薄膜电极.在光强为100mW/cm2的条件下,TiO
Let X be a non-primary Hopf Surface with Abelian fundamental group π1(X) ≌Z (+)Zm, L a line bundle on X, we give a formula for computing the dimension of coho
The main aim of this paper is to study the local anisotropic interpolation error estimates. We show that the interpolation of a nonconforming element satisfy th
氯化氢等气体的检测在环境监测和化学工业等许多领域中具有重要意义.本文介绍以玻璃光波导元件和消逝波的吸收为基本原理来检测氯化氢等酸性气体的一种新方法.钾离子交换玻璃
This paper is a further investigation of large deviations for sums of random variables Sn =n∑i=1 Xi and S(t)=N(t)∑i=1 Xi,(t≥0), where {Xn,n≥1} are independe
应用鞅不等式及Banach空间的几何性质,讨论了当Banach 空间X是p阶光滑时,取值于X上的Banach 值双鞅算子的a.e.收敛性.
In this paper, we establish sufficient conditions for the controllability of nonlinear neutral evolution equations with nonlocal conditions. The result is obtai
This paper is concerned with the distributional properties of a median unbiased estimator of ARCH(0,1) coefficient. The exact distribution of the estimator can