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由过渡金属与邻菲咯啉(Phen)反应,合成了配合物[Ni(Phen)2(H2O)]·2ClO4,并测定了它的红外光谱及晶体结构.结果表明:配合物属单斜晶系,空间群C2/c,其晶胞参数为:a=1 9159(4)nm,b=0 82271(17)nm,c=1 6170(4)nm;β=100 477(15)°,V=2 5063(9)nm3,Z=8,Dcald=1 491g·cm-3.该配合物由络阳离子Cu(Phen)2(H2O)2+和2个高氯酸根堆积而成,分子间通过π—π堆积作用而形成二维网结构.
The complex [Ni (Phen) 2 (H2O)] · 2ClO4 was synthesized by the reaction of transition metal with phenanthroline (Phen), and its infrared spectrum and crystal structure were also determined. The results show that the complex belongs to monoclinic The space group C2 / c has the unit cell parameters of a = 1 9159 (4) nm, b = 0 82271 (17) nm and c = 1 6170 (4) nm; V = 2 5063 (9) nm3, Z = 8 and Dcald = 1 491 g · cm-3. The complex is formed by the accumulation of the complex cation Cu (Phen) 2 (H2O) 2+ and 2 perchlorates, Through the π-π stacking effect and the formation of two-dimensional network structure.