Synthesis, Crystal Structure and Catalytic Activity Palladium(Ⅱ) Complexes Containing Bulky Azole Li

• 作 者: ZHANG Meng-Yao ZHANG Ying-Ying ZHANG Hui-Xin WANG Shen WANG Ya-Qi ZENG Yong-Fei LIU Gui-Yan
• 机 构: Tianjin Key Laboratory of Structure and Performance for Functional Molecules“,”Key Laboratory of Ino
• 出 处: 结构化学
• 发表日期: 2020年9期
• 关键词: palladium(Ⅱ) complexes crystal structure catalytic activity Suzuki-Miyaura cross

Bulky azole ligands in combination with PdCl2 provide three new palladium(Ⅱ) complexes.All these complexes,as pre-catalysts,have high catalytic efficiency for the Suzuki-Miyaura cross-coupling reactions of sterically hindered aryl chlorides and good to high yields are obtained with low catalysts loadings (0.1 mol％) under mild conditions in air.