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The aging behaviors of Ni-Cr-Al ternary alloy are studied at temperature 873 K based on the mean-field theory, and the early precipitation process is simulated at atomic-scale with microscopic phase-field model. The precipitation mechanism of the low supersaturated alloy Ni-12.2at. %Cr-7.8at. %Al is non-classical nucleation and growth, the L12 structure (Ni3Al) and D022 structure (Ni3Cr) phases precipitate simultaneously, a part of D022 phase transmits to Ll2 structure phase, and other part retains its previous structure. For high supersaturated alloy, congruent ordering appears first, then followed by spinodal decomposition, the nonstoicheometric ordered phases are produced in this process, which occurs before clustering. The precipitation mechanism of Ni-8at. %Cr-18at. % Al alloy is similar to Ni-10at. %Cr-12at. %AI alloy, but the ordering process of the former is ahead of the latter.
The aging behaviors of Ni-Cr-Al ternary alloys are studied at temperature 873 K based on the mean-field theory, and the early precipitation process is simulated at atomic-scale with microscopic phase-field model. The precipitation mechanism of the low supersaturated alloy Ni-12.2 at.% Cr-7.8 at.% Al is non-classical nucleation and growth, the L12 structure (Ni3Al) and D022 structure (Ni3Cr) phases precipitate simultaneously, a part of D022 phase transfer to L12 structure phase, and other part retains its previous structure. For high supersaturated alloy, congruent ordering appears first, then followed by spinodal decomposition, the nonstoicheometric ordered phases are produced in this process, which occurs before clustering. The precipitation mechanism of Ni-8at.% Cr-18at % Al alloy is similar to Ni-10at.% Cr-12at.% AI alloy, but the ordering process of the former is ahead of the latter.