【摘 要】
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Two homologous series of bent-shaped molecules composed of low bent-angle naphthalene central core and long alkoxy tail or alkylthio tail, N(1,7)-n-OPIMB and W(
【机 构】
：
School of Material Science and Engineering
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Two homologous series of bent-shaped molecules composed of low bent-angle naphthalene central core and long alkoxy tail or alkylthio tail, N(1,7)-n-OPIMB and W(1,7)-n-SPIMB (n = 20, 22), respectively, were synthesized. The mesomorphic properties were investigated by differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (XRD). Compared to the direct transition from the isotropic phase to the chiral B4 phase examined in N(1,7)-n-OPIMB, N(1,7)-n-SPIMB exhibited a rare Iso-Ncol-Colh-B4 phase sequence. The combination of the asymmetric low bent-angle 1,7-naphathalene central core and the flexible long alkylthio tail is considered to play an important role in the formation of such a novel phase sequence. (c) 2011 Mao Sheng Zhan. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
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