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The title compound [ClCH2(C7H6N2)]NO3 has been prepared and characterized by elemental analysis and X-ray studies. It crystallizes in the monoclinic system, space group P21/n with a = 7.4189(3), b =15.3064(6), c = 9.2657(3) ? b = 102.449(2)? C8H8ClN3O3, Mr = 229.62, V = 1027.44(7) 3, Z = 4, Dc = 1.484 g/cm3, F(000) = 472, = 0.363 mm-1, R = 0.0671 and wR = 0.1546. The crystal structure consists of discrete 2-chloromethyl-1H-benzimidazole cations and NO3- anions. The benzimidazole ring with the conjunction carbon atom C(1) is fairly planar, with the deviation from the least plane through the ring atoms is smaller than 0.010(3) ? The analytical results of crystal structure show that three different non-covalent interactions in the compound, NH…O intermolecular hydrogen bonds, CH…O interaction and p-p stacking interaction, play an important role in the crystal packing.
It crystallizes in the monoclinic system, space group P21 / n with a = 7.4189 (3), b = 15.3064 (6) The title compound [ClCH2 (C7H6N2)] NO3 has been prepared and characterized by elemental analysis and X- , C = 9.2657 (3)? b = 102.449 (2)? C8H8ClN3O3, Mr = 229.62, V = 1027.44 (7) 3, Z = 4, Dc = 1.484 g / cm3, F (000) = 472, = 0.363 mm -1, R = 0.0671 and wR = 0.1546. The crystal structure consists of discrete 2-chloromethyl-1H-benzimidazole cations and NO 3- anions. The benzimidazole ring with the conjunction carbon atom C (1) is fairly planar, with the deviation from The least squares of the ring atoms is smaller than 0.010 (3)? The analytical results of crystal structure show that three different non-covalent interactions in the compound, NH ... O intermolecular hydrogen bonds, CH ... O interaction and pp stacking interaction, play an important role in the crystal packing.