‘Whole-molecule Disorder’ Refinement of 4-（4-Hydroxybenzylideneiminio）phenol Hemichloride Hemihydrox

• 作 者: NG Seik Weng
• 机 构: DepartmentofChemistry
• 出 处: 结构化学
• 发表日期: 2011年9期
• 关键词: 分子 苯酚 氢氧化钠 三斜晶系 盐离子 芳香环 氧原子 阳离子 whole-molecule disorder
• 基金项目: ACKNOWLEDGEMENTSI thank Dr. M. Raza Shah of the HEJ Research Institute of Chemistry, University of Karachi, Pakistan, for providing the crystal, and the University of Malaya for supporting this study.

The two independent cations of the salt, [HO-C6H4-CH=NH-C6H4-OH]·1/2OH·1/2Cl, are both disordered about an axis connecting the two oxygen atoms at the para-positions of the aromatic rings, the disorder being in a 83:17 ratio in one cation and 91