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A binuclear complex [Cu2(phen)2(ip)(Hip)2]·4H2O has been synthesized by the reaction of Cu(CH3COO)2·H2O, phen(1,10-phenanthroline) and isophthalic acid (H2ip) under hydrothermal condition. Elemental analysis, IR spectra and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure. Crystal data for this complex: mono- clinic, space group C2/c, a = 19.214(3), b = 10.6973(14), c = 22.567(3) , β = 105.081(2)°, C24H19N2O8Cu, Mr = 526.95, Z = 8, F(000) = 2160, V = 4478.6(10) 3, Dc = 1.563 g/cm3, μ = 1.030 mm-1, –24≤h≤16, –13≤k≤13, –28≤l≤28, R = 0.0369 and wR = 0.0819 for 4615 (Rint = 1.0357) independent reflections and 3290 observed ones (I > 2σ(I)). Structural analysis shows that coordination geometry of Cu(Ⅱ) is a planar square, and the title complex exhibits a 2-D framework supramolecular structure by hydrogen bonds and π-π stacking interactions.
A binuclear complex [Cu2 (phen) 2 (ip) (Hip) 2] · 4H2O has been synthesized by the reaction of Cu (CH3COO) 2 · H2O, phen (1,10-phenanthroline) and isophthalic acid (H2ip) Elemental analysis, IR spectra and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure. Crystal data for this complex: mono-clinic, space group C2 / c, a = 19.214 (3), b = 10.6973 (14), c = 22.567 (3) , β = 105.081 (2) ° C24H19N2O8Cu Mr = 526.95 Z = 8 F000 = 2160 V = 4478.6 103 Dc = 1.563 g / cm3, μ = 1.030 mm-1, -24≤h≤16, -13≤k≤13, -28≤l≤28, R = 0.0369 and wR = 0.0819 for 4615 (Rint = 1.0357) independent reflections and 3290 observed ones (I> 2σ (I)). Structural analysis shows that the coordination geometry of Cu (II) is a planar square, and the title complex exhibits a 2-D framework supramolecular structure by hydrogen bonds and π-π stacking interactions.