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Pure phase, regular shape and well crystallized nanorods of p-type semiconductor CaFe_2O_4 have been fabricated for the first time by a facile molten salt assisted method, as confirmed by XRD, TEM, SEM and HRTEM. UV-vis diffuse reflectance spectra and Mott–Schottky plots show that the band structure of the CaFe_2O_4 nanorods is narrower than that of the CaFe_2O_4 nanoparticles synthesized by conventional method. The enhancement of the visible-light absorption is due to narrowness of the band gap in CaFe_2O_4 nanorods. The appropriate ratio between the molten salt and the CaFe_2O_4 precursors plays an important role in inhibiting the growth of the crystals along the(201) plane to give the desired nanorod morphology. This work not only demonstrates that highly pure p-type CaFe_2O_4 semiconductor with tunable band structure and morphology could be obtained using the molten salt strategy, but also affirms that the bandgap of a semiconductor may be tunable by monitoring the growth of a particular crystal plane.Furthermore, the facile eutectic molten salt method developed in this work may be further extended to fabricate some other semiconductor nanomaterials with a diversity of morphologies.
Pure phase, regular shape and well crystallized nanorods of p-type semiconductor CaFe 2 O 4 have been fabricated for the first time by a facile molten salt assisted method, as confirmed by XRD, TEM, SEM and HRTEM. UV-vis diffuse reflectance spectra and Mott- Schottky plots show that the band structure of the CaFe 2 O 4 nanorods is narrower than that of the CaFe 2 O 4 nanoparticles synthesized by conventional method. The enhancement of the visible-light absorption is due to narrowness of the band gap in CaFe 2 O 4 nanorods. The appropriate ratio between the molten salt and the CaFe_2O_4 precursors plays an important role in inhibiting the growth of the crystals along the (201) plane to give the desired nanorod morphology. This work not only demonstrates that highly pure p-type CaFe_2O_4 semiconductor with tunable band structure and morphology could be obtained using the molten salt strategy, but also affirms that the band gap of a semiconductor may be tunable by monitoring the growth of a pa rticular crystal plane.Furthermore, the facile eutectic molten salt method developed in this work may be further extended to fabricate some other semiconductor nanomaterials with a diversity of morphologies.