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利用水热方法合成了三维多酸基无机-有机杂化化合物[CuⅠ6(pyz)6][(PMo12O40)2]·11H2O(pyz=吡嗪),并通过单晶X射线衍射、红外光谱、元素分析、热重分析和粉末X射线衍射等方法对其进行了表征.结构分析表明该化合物属于立方晶系,Ia-3d空间群,晶胞参数a=b=c=2.602 66(3)nm,α=β=γ=90°,V=17.630 0(4)nm3,Z=8,R1=0.052 7,wR2=0.137 8.进一步研究了该化合物的电化学性质,结果表明其在电催化氧化葡萄糖反应中具有良好的活性.
Three-dimensional polyoxometalate inorganic-organic hybrid compounds [CuI6 (pyz) 6] [(PMo12O40) 2] · 11H2O (pyz = pyrazine) were synthesized by hydrothermal method and characterized by X-ray single crystal diffraction, The structure analysis showed that the compound belongs to the cubic system, the Ia-3d space group, the unit cell parameter a = b = c = 2.602 66 (3) nm, α = β = γ = 90 °, V = 17.630 0 (4) nm3, Z = 8, R1 = 0.052 7, wR2 = 0.137 8. The electrochemical properties of the compound were further studied and the results showed that the electrocatalytic oxidation of glucose The reaction has good activity.