Hydrothermal Synthesis and Structural Characterization of two Hybrid Keggin-based Polyoxometalates

• 作 者: LI Bing ZHENG Shou-Tian YANG G
• 机 构: StateKeyLaboratoryofStructuralChemistry,DepartmentofChemistry
• 出 处: 结构化学
• 发表日期: 2009年5期
• 关键词: 水热合成 多金属氧酸盐 双杂交 结构表征 KEGGIN n型 联吡啶 晶体学分析 polyoxometalates hydrothermal synthesi
• 基金项目: Supported by the National Natural Science Fund for Distinguished Young Scholars of China （No. 20725101）, the NNSFC （Nos. 50872133 and20821061）, the 973 Program （No. 2006CB932904）, the NSF of Fujian Pr

Two new hybrid polyoxotungstates,[Co(2,2′-bipy)3][α-H5PW11CoO40]·3H2O 1 and [Fe(2,2′-bipy)3]2[α-HBW12O40]·2.5H2O 2(2,2′-bipy = 2,2′-dipyridyl),have been hydrothermally synthesized and characterized by IR,TGA and single-crystal X-ray structural a