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在CH3CH2OH/CH3OH溶剂中合成了标题配合物[Mn(H2O)6](C13H10NO4S)2{C13H10NO4S=4-[(2-羟基-亚苄基)-氨基]-苯磺酸阴离子},利用元素分析、红外光谱、X-射线单晶衍射和热分析等手段对配合物进行了表征.结果表明,该化合物属单斜晶系,空间群为P121/c1,其晶胞参数:a=0.633 48(2)nm,b=3.564 08(8)nm,c=0.944 25(3)nm,β=131.790(2)°,V=1.589 53(8)nm3,Z=2.在标题配合物中,Mn2+离子与6个配位水的6个氧原子配位形成畸变的八面体构型.脱质子的席夫碱并未参与配位,而是作为抗衡阴离子存在于配合物晶体结构中,从而使整个配合物呈电中性.
The title complex [Mn (H2O) 6] (C13H10NO4S) 2 {C13H10NO4S = 4 - [(2-hydroxy-benzylidene) -amino] -benzenesulfonate anion was synthesized in CH3CH2OH / , IR, X-ray single crystal diffraction and thermal analysis were used to characterize the complex. The results show that the compound belongs to monoclinic system with space group P121 / c1 and its unit cell parameters are as follows: a = 0.63348 ( 2) nm, b = 3.564 08 (8) nm, c = 0.944 25 (3) nm, β = 131.790 (2) ° and V = 1.589 53 (8) nm3 and Z = 2. In the title complexes, The ions coordinated with the six oxygen atoms of six coordination water to form a distorted octahedral configuration.The deprotonated Schiff base did not participate in coordination but existed as a counter anion in the crystal structure of the complex, The complex is electrically neutral.