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应用Ｃｏｒｎｉｎｇ一价阳离子选择电极（Ｍ＋～ＩＳＥ）和Ｏｒｉｏｎ氯离子选择性电极（Ｃｌ－～ＩＳＥ）组成可逆电池，即Ｃｌ－～ＩＳＥ／ＲｂＣｌ（ｍ），Ｈ２Ｏ（１－ｘ），ＤＭＦ（ｘ）／Ｍ＋～ＩＳＥ通过测定上述测量电池的标准电动势（Ｅ０ｍ／ｍＶ），根据溶液热力学原理，运用扩展的Ｄｅｂｙｅ～Ｈüｃｋｅｌ公式，计算求得了ＲｂＣｌ由Ｈ２Ｏ至（Ｈ２Ｏ～ＤＭＦ）混合溶剂的标准迁移自由能（ΔＧ０ｔ／ｋＪ·ｍｏｌ－１）和ＲｂＣｌ在（Ｈ２Ｏ～ＤＭＦ）混合溶剂中的活度系数（γ±），并对上述热力学性质随混合溶剂组成的变化规律进行了初步的讨论．
The reversible cells were composed of Corning monovalent cation selective electrode (M + ~ ISE) and Orion chloride selective electrode (Cl- ~ ISE), namely Cl- ~ ISE / RbCl ) / M + ~ ISE The standard migration of RbCl from H2O to (H2O ~ DMF) was calculated by measuring the standard electromotive force (E0m / mV) of the above measured cell and the extended Debye ~ Hückel equation according to the thermodynamics of the solution The activity coefficient (γ ±) of ΔG0t / kJ · mol-1 and RbCl in (H2O ~ DMF) mixed solvents was also discussed. The thermodynamic properties of the mixed solvents were also discussed.