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The early Mesozoic granodiorites (ca. 165 Ma) in the northeastern Hunan Province (NEH) have SiO2=65.4-69.65%, K2O/Na2O=0.95-1.38 and K2O+Na2O>6%, A/CNK=0.96-1.13 and belong to metaluminous high-K calc-alkaline series. They are characterized by LREE and LI